Kostya Trachenko
Kostya Trachenko received his PhD from Cambridge University in 2000 and MSc from L'viv University, Ukraine. He subsequently held a Research Fellowship in Darwin College, Cambridge, and an EPSRC Advanced Research Fellowship. He joined Queen Mary University of London in 2010 where he has been a Professor of Physics.
Trachenko's research interests mostly lie in theoretical and computational condensed matter physics:
- fundamental theory of states of matter including theory of liquids and supercritical fluids
- theory of melting
- links between fundamental physical constants and system properties and the origin of fundamental constants
- links between field theory and condensed matter physics
- high pressure
- glasses and glass transition
- radiation damage effects including in nuclear and fusion energy and waste forms
Trachenko's work won the top 10 Physics Breakthrough award and the CCP5 prize for "outstanding contributions to theory and modelling of condensed matter phases including liquid state theory".
Trachenko is known for developing theory of the liquid state, the long-standing problem in physics. The statement of this problem, together with its solution, are outlined in:
- the Preface and Introduction of the 2023 CUP book "Theory of liquids: from excitations to thermodynamics" (these two chapters, together with other information such as reviews, are available as the "Front matter" and "Marketing Excerpt" under the Contents/Look inside tab on the CUP book webpage.)
- the 1584 CUP blog
- the arxiv paper which includes the Preface, Introduction and experimental sections of the book
Highlights in news and media:
- Theory of melting in New Scientist and America Online
- Constraints on fundamental constants from bio-friendly viscosity and diffusion in Physics World: "Evolution may explain values of the fundamental constants"
- A supercritical step for fundamental physics with green prospects
- Award of the top 10 Physics Breakthroughs
- Upper bound on the speed of sound in the Economist: "Does sound, like light, have a maximum speed? ("MaxMach" in the print edition), Physics World: "Fundamental constants set upper limit for the speed of sound", Science News, Sky News and Daily Mail
- Viscosity of quark-gluon plasma in Physics World and Futurism: "The early Universe was a vast liquid ocean"
- Minimal quantum viscosity in Physics Today and Physics World: "Fluids only get so runny as physicists put a universal lower limit on viscosity"
- Vacuum energy gets flexible - IoP news
- Slow bitumen flow in BBC Feature Article "Tedium, tragedy and tar: The slowest drops in science" and New Scientist.
- New understanding of supercritical state in Physics Today
- Phonon theory of liquid thermodynamics in Physics World
Representative papers
Theory of melting
K Trachenko, Theory of melting lines, Physical Review E 2024 and highlights in New Scientist and America Online
Fundamental physical constants and condensed matter including the liquid state
K Trachenko, Constraints on fundamental constants from bio-friendly viscosity and diffusion, Science Advances 2023 and highlights in in Physics World
K Trachenko, Properties of condensed matter from fundamental physical constants, Advances in Physics 2023
K Trachenko and V Brazhkin, The quantum mechanics of viscosity, Physics Today 2021
Top 10 Breakthroughs in 2020 K Trachenko, B Monserrat, C J Pickard and V Brazhkin, Speed of sound from fundamental physical constants, Science Advances 2020 and highlights in the Economist, ("MaxMach" in the Economist print edition), Physics World, Science News, Sky News and Daily Mail
K Trachenko and V Brazhkin, Minimal quantum viscosity from fundamental physical constants, Science Advances 2020 and highlights in Physics World and AAAS.
K Trachenko, V Brazhkin and M Baggioli, Similarity between the kinematic viscosity of quark-gluon plasma and liquids at the viscosity minimum, SciPost Physics 2021 and the highlights in Physics World, Futurism and AAAS
K Trachenko, M Baggioli, K Behnia and V Brazhkin, Universal lower bounds on energy and momentum diffusion in liquids, Physical Review B 2021
Theory of liquids
K Trachenko, Heat capacity of liquids: an approach from the solid phase, Physical Review B 2008
K Trachenko and V Brazhkin, Collective modes and thermodynamics of the liquid state, Reports on Progress in Physics 2016
C Yang, M Dove, V Brazhkin and K Trachenko, Emergence and evolution of the k-gap in spectra of liquid and supercritical states, Physical Review Letters 2017
M Baggioli, M Vasin V Brazhkin and K Trachenko, Gapped momentum states, Physics Reports 2020
New understanding of the supercritical state of matter
C Cockrell, V Brazhkin and K Trachenko, Transition in the supercritical state of matter: review of experimental evidence, Physics Reports 2021
V Brazhkin and K Trachenko, What separates a liquid from a gas? Physics Today 2012
Problem of liquid-glass transition
K Trachenko and V Brazhkin, Heat capacity at the glass transition, Physical Review B 2011
K Trachenko, Slow dynamics and stress relaxation in a liquid as an elastic medium, Physical Review B 2007
Radiation damage
E Zarkadoula et al, The nature of the high-energy radiation damage in iron, IoP Select, J. Phys.: Condens. Matt. 2013
K Trachenko, I Todorov, M Dove, E Artacho and W Smith, Atomistic simulations of resistance to amorphization by radiation damage, Physical Review B 2006
K Trachenko, M Pruneda, E Artacho and M Dove, How the nature of the chemical bond governs resistance to amorphization by radiation damage, Physical Review B 2005
Inter-disciplinary, including links to field theory and other areas
M Baggioli, M Vasin, V Brazhkin and K. Trachenko, Field theory of dissipative systems with gapped momentum states, Physical Review D 2020
K Trachenko, Stable equilibrium point and oscillatory motion of the Universe in a model with variable vacuum energy, Physical Review D 2017
Education
A. T. Widdicombe et al, Measurement of bitumen viscosity in a room-temperature drop experiment: student education, public outreach and modern science in one, Physics Education 2014
Summary of research in papers above
Long-standing melting problem and theory of melting
There has been a long-standing problem in understanding basic states of matter: solids, liquids and gases. These states are understood on the basis of the pressure-temperature phase diagram where different states are separated from each other by phase transition lines. Two of these lines, the solid-gas and liquid-gas lines, were understood and their functional form was worked out long ago. The third line, the solid-liquid melting line, has remained completely mysterious. It is interesting that in this age of scientific and technological development, something as basic as theoretical understanding of the pressure-temperature dependence of the melting line was still absent.
There are at least two reasons why it is important to solve the melting problem. The first is related to fundamental science and fundamental understanding of the basic states of matter. We can’t understand these states if we don’t know where the melting line is on the phase diagram. The second reason is related to applications: predicting phase diagrams is the key area in materials science. There is an active search for new functional and high-performance materials (eg “Materials genome” project in the US), but in order to predict the stability range of a new material we need to be able to predict its melting point and its melting line. This includes new advanced materials with tailored properties in areas such as drug development and areas where high-performance materials (used in, for example, energy, environmental and space applications) are subject to high pressure and temperature. Knowing the functional form of the melting line immediately tells us up to what temperature the system remains as a solid before it melts.
In order to solve the melting problem, one needs to solve the Clausius-Clapeyron (CC) equation written in 1834 and about 200 years ago. This was done for the solid-gas and liquid-gas lines long ago because solid-gas and liquid-gas transitions involve the gas state which is uncondensed and has no cohesion energy. This greatly simplifies the solution of the CC equation because the latent heat involved in the solid-gas and liquid-gas transitions is related to the energy of cohesion in a condensed phase (solid or liquid). This simplification does not apply to the melting line because both solids and liquids are condensed states. So in order to solve the CC equation, we need to explicitly know the equation governing liquid thermodynamic properties in general form as well as the liquid equation of state. And this problem of liquid theory was exactly the reason why the melting problem remained unsolved for 200 years.
Many physics luminaries (Brillouin, Frenkel etc) worked on the melting problem, including Nobel-prize laureates such as Born. In order to solve the CC equation, one needs to know another equation: the equation for liquid thermodynamic properties such as entropy. And another group of physics luminaries and Nobel laureates among them (Landau, Lifshitz and Pitaevskii) have stated that deriving this equation for liquid properties in general form is impossible. If this is true then solving the melting problem is also impossible.
Over a few years, me and my collaborators thought hard and developed a new understanding of the liquid state. This has given us an advantage in solving the melting problem. I realised that differentiating the CC equation and using the similarity of specific heats of solids and liquids close to melting (this similarity is backed up by our recent theory of liquids and numerous experiments) gives a new melting equation that can be solved.
The solution (Physical Review E 2024) gives the first important result: the analytical function of the melting line turns out to have a simple quadratic, parabolic, form: pressure depends on temperature quadratically along the melting line. Second, it turns out that the parameters of this parabola are governed by fundamental physical constants: the Planck constant and electron charge and mass. Therefore, all melting lines have this fundamental unity of properties. These two results are confirmed by experimental melting lines in several different types of liquids, including noble, molecular, network and metallic.
Properties of condensed matter and fundamental physical constants
Liquid viscosity is strongly system-dependent and also depends on temperature and pressure. It is not possible to calculate liquid viscosity in general form due to strong interactions, the same problem that exists for liquid thermodynamics (see below). It turns out that liquid viscosity at its minimum is universal. We have recently shown how fundamental physical constants provide the lower bound of liquid viscosity (Science Advances 2020). This minimal viscosity is a new quantum property, featuring the Planck constant.
Interestingly, EM Purcell noted that "the viscosities have a big range but they stop at the same place" (Am. J. Phys., 1977), adding that he does not understand this and that Weisskopf has explained it to him (we didn't find this Weisskopf's explanation). Our results provide the answer to this question (Physics Today 2021).
It turns out that the same theoretical minimum for viscosity in terms of fundamental constants applies to a very different property: thermal conductivity and thermal diffusivity (Physical Review B 2021). Fundamental constants also govern the maximal velocity gradient that can be set up by a biochemical machine in cells using chemical energy (Science Advances 2023).
We have similarly applied our ideas to relate another property, the speed of sound in condensed matter phases to fundamental physical constants. We have found (Science Advances 2020) that fundamental constants give the upper bound to the speed of sound in solids and liquids of about 36 km/s. The ratio of this bound to the speed of light depends only on two important dimensionless constants, the fine structure constant and the proton-to-electron mass ratio.
Having realised that several other important properties of condensed matter are governed by fundamental physical constants, I have written a review of this topic (Advances in Physics 2023).
Theory of liquid thermodynamics
One of the triumphs of physics has been the theory of solid state developed at the beginning of the last century. This provided a fundamental understanding of the basic properties of solid matter such as the ability to absorb and transfer heat. Solid state theory was preceded by the equally successful theory of gases. But when we turn to the third main phase of matter, the liquid phase, most textbooks remain silent about the most basic liquid properties such as heat capacity. Paradoxical though it may seem in this age of scientific and technological advancement, we still do not understand the most basic aspects of liquid behaviour. The combination of strong interactions with large atomic rearrangements has proved to be the ultimate obstacle to developing a theory of liquids. This was famously summarized as the "no small parameter" problem (eg by Pitaevskii). Landau and Lifshitz repeatedly assert that liquid energy and heat capacity can not be calculated in general form, contrary to solids and gases (Statistical Physics, Pergamon Press, 1969, par. 66 and par. 74). I have proposed that contrary to this statement, liquid energy and heat capacity can in fact be calculated and understood.
The argument of Landau, Lifshitz and Pitaevskii concerns the approach to liquids in which the interaction energy is calculated in addition to the gas kinetic energy, as an integral over interatomic potentials and correlations functions. This general approach formed the basis for previous theories of liquids. Apart from the problem of being system-specific as discussed by L&L, there are other important disadvantages of this approach: (a) interatomic potentials and correlations functions are not generally available, consequently, apart from very simple and exotic liquids such as those composed of noble elements, it has not been possible to calculate liquid energy and heat capacity; (b) calculations become difficult beyond simple cases and approximations difficult to control; (c) it is not easy to see how the results are consistent with large experimental decrease of liquid heat capacity over a wide temperature range.
Together with collaborators, I have developed theory of liquids based on excitations, phonons. Differently from solids where the number of phonons is fixed to 3N, this number is variable in liquids and reduces with temperature. This addresses the problem set out by Landau, Lifshitz and Pitaevskii: there is in fact a small parameter in the liquid theory, but this parameter operates in a variable phase space. This gives the key to liquid theory, as discussed in my book (Cambridge University Press 2023). This theory for the first time explains a wide range of experimental data in many real liquids, including their specific heats.
"The most detailed and rigorous test of the phonon theory of thermodynamics" was undertaken (J Proctor, Physics of Fluids 2020 and book on liquid and supercritical states 2020 and Proctor's book ). Proctor notes that the theory is falsifiable but tests did not falsify it.
A new line on a phase diagram of matter above the critical point: the Frenkel line
According to previous textbook understanding, no differences can be made between a gas and a liquid above the critical point, an abrupt terminus of the liquid-gas coexisting line. Recently, we have discovered that this is not the case, and that the phase diagram of matter should be modified. We have proposed that a new line ("Frenkel line") exists on the phase diagram above the critical point at arbitrarily high pressure and temperature, and which separates two physically distinct states of matter (Physics Today 2012). Crossing the line corresponds to qualitative changes of physical properties of the system.
The Frenkel line has been since experimentally confirmed in supercritical Ne, CH4, CO2, N2, C2H6 and H2O using X-ray, neutron and Raman scattering. We have written a review discussing this evidence (Physics Reports 2021).
Field theory of liquids and dissipation effects
I have proposed a Lagrangian theory of liquid dynamics involving two scalar fields. Dissipation was believed to be hard to describe by a Lagrangian, however in my theory the energy dissipated by one field is taken up by the second field (Physics Reports 2020, Physical Reiew D 2020). The theory results in gapped momentum states (GMS), the effect which we now realize extends beyond liquids and into other areas such as plasma, holographic models, relativistic hydrodynamics and so on.
The problem of glass transition
The problem of glass transition was considered as one of the deepest and most interesting challenges in physics. The problem consists of two parts, dynamic and thermodynamic. The thermodynamic part of the problem of glass transition is related to two widely observed experimental facts: (a) heat capacity changes with a jump at the glass transition temperature Tg, and (b) no distinct solid glass phase has been identified experimentally or suggested theoretically. Therefore, the problem is to explain the jump of heat capacity without asserting the existence of a distinct solid glass phase. This problem is also common to other disordered systems, including spin glasses. I have proposed that if, as is the case, Tg is defined as the temperature at which the liquid stops relaxing at the experimental time scale, the jump of heat capacity at Tg follows as a necessary consequence due to the change of system's elastic, vibrational and thermal properties. The resulting equations have no fitting parameters, and compare well with experimental results. This theory explains widely observed time-dependent effects of glass transition, including logarithmic increase of Tg with the quench rate, and identifies distinct regimes of relaxation (Physical Review B, 2011)
The dynamic part of the problem of glass transition is to explain the physical origin of several famous relaxation laws and dynamic effects that liquids show in the glass transformation range: the Vogel-Fulcher-Tammann law, stretched-exponential relaxation, dynamic crossovers etc. These phenomena are universal and are seen in other systems as well (e.g. spin glasses), yet their physical origin is not understood. I have proposed a solution to this problem based on elastic interactions in a liquid. The solution is based on a non-trivial way in which high-frequency elastic waves propagate in a liquid. Crucially, the propagation range of these waves increases with liquid viscosity. This is in contrast to frequently discussed hydrodynamic waves, whose propagation range decreases with viscosity.
Radiation damage
Radiation damage is a large and important area in science and technology, and has far-reaching consequences for materials performance in a wide range of applications, including immobilization of nuclear waste and future fusion reactors. This performance crucially depends on whether a material is amorphizable by radiation damage or is able to recover back to crystal. The phenomenon of resistance to amorphization by radiation damage remains largely not understood from theoretical standpoint. I elucidated the phenomenon of resistance to amorphization by radiation damage using massive parallel molecular dynamics simulations. This was supported by quantum-mechanical calculations of electronic structure.